After you've created a free account, you have to log into your Dashboard, go to the "Payments" section and select "Withdraw". 
If you don't have a verified account and you want to withdraw more than the default limit, you need to have your account verified How to get my identity verified?.

Choose your withdrawal method and fill in the form below (Paxum/FirstChoicePay e-mail | ePayments e-Wallet | Bitcoin Address) and click "Submit".

The number of days from the withdraw request moment until the withdraw payout moment is 14 days